Carbonyl[4-(2,3-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O](triphenylphosphine-κP)rhodium(I)
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چکیده
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra-molecular hydrogen bonding is observed between a C-H group of the triphenyl-phosphine unit and the O atom of the enamino-ketonate ligand.
منابع مشابه
Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl-phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol-ecule, lying about an inversion center, of the ace...
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